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Preheat the oven to 350 F/180 C. (If you are using a dark or nonstick pan, reduce the heat by 25 F).
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Lightly grease and flour a Bundt pan, making sure to tap out any excess flour. Or grease two 9-inch (23 centimeters) layer cake pans, and line the bottom of each with a parchment paper circle.
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Grease the parchment circles.
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Set aside.
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In a double-boiler or microwave, melt the chocolate. Alternatively, place the chocolate in a heatproof bowl, and set it over a small saucepan of gently simmering water (the bottom of the bowl should rest in the saucepan, but should not touch the water).
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Stir constantly until the chocolate melts, then remove the bowl from the saucepan and set aside.
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In a large bowl, whisk together the flour, sugar, cocoa powder, baking powder, baking soda, instant espresso, and salt.
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In another bowl, whisk together the oil, orange juice, water, eggs, and vanilla.
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Add the wet ingredients to the dry, and mix just until combined.
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Add the melted chocolate, and stir just until it is well incorporated and the batter is smooth.
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Pour the batter in to the prepared pan(s).
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Bake in the preheated oven until a tester inserted in the center of the cake comes out clean–about 50 to 60 minutes if using a Bundt pan, or 35 to 45 minutes if using layer cake pans.
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Cool completely on a wire rack.
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Glaze or frost as desired. Enjoy!
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