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Preheat oven to 350 degrees F. Coat a 9- x 13-inch baking dish with cooking spray.
Place melted butter in a large bowl; add cocoa and stir until well blended. Add sugar; mix well. Add eggs, one at a time, beating well after each addition. Add flour, vanilla, and salt; stir just until combined. Stir in chocolate chunks and nuts, if desired. Spread batter in baking dish.
Bake about 40 minutes, or until a toothpick inserted in center comes out clean. Let cool, then cut into serving-sized pieces.
Notes
Semisweet chocolate chips can be substituted for the chocolate chunks.
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